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Question

Explain Be has High Ionisation enthalpy than B .

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Solution

The difference in ionization energybetween B and Be can be explained by detailing their respective electron configurations:

Be: 1s22s2
B: 1s22s22p1

Notice that Be has a stable electron configuration, which means that more energy is required to remove an electron from it. On the other hand, B's ionization energy is smaller because of the electron present in its p-orbital.

Since p-orbitals are higher in energy than s-orbital, therefore less stable, it is easier for an electron to be removed from a p-orbital. Electrons located in p-orbitals are further away from the nucleus, which means that they can withstand its effective nuclear charge better ⇔ more easy to remove from the atom.

Losing an electron from its outermost shell will make B more stable, since it will be lower in energy.


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