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Question

For the conversion:MeMgBr2Methylpropan2ol in dry ether and then workup, the appropriate reagent used is:

A
Propanol
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B
Acetaldehyde
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C
Acetone
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D
Ethanol
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Solution

The correct option is C Acetone
Grignard reagent in presence of alcohol(propanol or ethanol) produces alkane by acid-base reaction. The product formed by MeMgBr with acetaldehyde is Butan-2-ol and with acetone, it is 2-Methylpropan-2-ol.
Hence, (c) is correct.

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