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Byju's Answer
Standard XII
Chemistry
Equilibrium Constant from Nernst Equation
For the equil...
Question
For the equilibrium,
2
H
2
O
⇌
H
3
O
+
+
O
H
−
, the value of
Δ
G
o
at 298 K is approximately :
A
−
80
k
J
m
o
l
−
1
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B
−
100
k
J
m
o
l
−
1
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C
100
k
J
m
o
l
−
1
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D
80
k
J
m
o
l
−
1
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Solution
The correct option is
A
80
k
J
m
o
l
−
1
2
H
2
O
=
H
3
O
+
+
O
H
−
K
=
10
−
14
Δ
G
o
=
−
R
T
ℓ
n
K
=
−
8.314
1000
×
298
×
ℓ
n
10
−
14
=
80
K
J
/
M
o
l
e
Therefore, option is D.
Suggest Corrections
0
Similar questions
Q.
Of the following reactions, the reaction with the largest equilibrium constant is:
(i) A
⇌
B;
Δ
G
o
=
250
k
J
m
o
l
−
1
(ii) D
⇌
E;
Δ
G
o
=
−
100
k
J
m
o
l
−
1
(iii) F
⇌
G;
Δ
G
o
=
−
150
k
J
m
o
l
−
1
(iv) M
⇌
N;
Δ
G
o
=
150
k
J
m
o
l
−
1
Q.
For the equilibrium
N
2
O
4
⇌
2
N
O
2
(
G
o
N
2
O
4
)
298
K
=
100
k
J
m
o
l
−
1
a
n
d
(
G
o
N
O
2
)
298
K
=
50
k
J
m
o
l
−
1
.
When 5 mole/litre of each is taken, calculate the value of
△
G
in
k
J
m
o
l
−
1
for the reaction at 298 K.(nearest integer)
Q.
For the equilibrium at
298
K;
N
2
O
4
(
g
)
⇌
2
N
O
2
(
g
)
;
G
⊖
N
2
O
4
=
100
k
J
m
o
l
−
1
and
G
⊖
N
O
2
=
50
k
J
m
o
l
−
1
. If 5 mol of
N
2
O
4
and 2 moles of
N
O
2
are taken initially in one litre container than which statement are correct
Q.
A hydrogenation reaction is carried out at 500 K. If the same reaction is carried out in the presence of a catalyst at the same rate, the temperature required is 400 K. Calculate the activation energy of the reaction at 500 K, if the catalyst lowers the activation barrier by
20
k
J
m
o
l
−
1
.
Q.
For the equilibrium
N
2
O
4
⇌
2
N
O
2
(
G
o
N
2
O
4
)
298
K
=
100
k
J
m
o
l
−
1
a
n
d
(
G
o
N
O
2
)
298
K
=
50
k
J
m
o
l
−
1
.
When 5 mole/litre of each is taken, calculate the value of
△
G
in
k
J
m
o
l
−
1
for the reaction at 298 K.(nearest integer)
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