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Question

Formation of NO2F from NO2 and F2 as per the reaction 2NO2(g)+F2(g)2NO2F(g) is a second order reaction, first order with respect to NO2 and first order with respect to F2. If NO2 and F2 are present in a closed vessel in ratio 2:1 maintained at a constant temperature with an initial total pressure of 3 atm., what will be the total pressure in the vessel after the reaction is complete?

A
1 atm
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B
2 atm
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C
2.5 atm
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D
3 atm
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Solution

The correct option is B 2 atm
2NO2(g)+F2(g)2NO2F(g)
I=[NO2][F2]
2 atm of NO2 uses 1 atm of F2
Hence, results in formation of 2 atm of NO2F.

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