From among the following choose the solutions with positive and negative deviations ROH+ROR RSH+ROR CHCl3 + CH3COCH3 HF +ROH Explain.

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C H C l_{3} + C H_{3} C O C H_{3}

Column - I	Column - II
a) A nearly ideal solution	p) $H_{2} O + C_{2} H_{5} O H$
b) A solution showing positive deviation	q) $C_{6} H_{6} + C_{6} H_{5} C H_{3}$
c) A solution showing negative deviation	r) $C_{6} H_{6} + C H C l_{3}$
d) An azeotropic mixture	s) $C H_{3} C O C H_{3}$ + $C_{2} H_{5} O H$
	t) $Δ H$ and $Δ V$ are positive
	u) $Δ H$ and $Δ V$ are negative

R O H

R^{'} M g X

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