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Question

How many products are produced respectively when optically pure glucose and fructose are reduced one by one by NaBH4?

A
1 & 1
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B
2 & 2
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C
1 & 2
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D
2 & 1
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Solution

The correct option is C 1 & 2
NaBH4 reduces aldehyde group of glucose into alcohol and form only one product.
NaBH4 reduces keto group of fructose into alcohol, but forms two product, as-
NaBH4 can attack keto group from both side and form D-mannitol and D-sorbital.

1119118_993226_ans_fdd5c51f677d42e89c870fb503e9cad7.jpg

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