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Question

How would you balance the following equation: Fe+O2Fe2O3?

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Solution

Step 1: Tally the number of atoms based on subscript.
Fe+O2Fe2O3 (unbalanced)
left side: Fe=1;O=2
right side: Fe=2;O=3

Step 2: Start balancing the simple molecules first, in this case the O2
Fe+3O2Fe2O3
left side: Fe=1;O=2×3=6
right side: Fe=2;O=3

Since there are now 6 O atoms on the left, there must also be 6 O atoms on the right. Notice that the right hand is one big molecule so whatever coefficient we would use to balance the O atoms, we would also need to apply to the bonded Fe atom.

Fe+3O22Fe2O3
left side: Fe=1;O=2×3=6
right side: Fe=2×2=4;O=3×2=6

Step 3: Now balance the rest of the equation.
4Fe+3O22Fe2O3
left side: Fe=1×4=4;O=2×3=6
right side: Fe=2×2=4;O=3×2=6

The equation is now balanced.

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