How would you balance the following equation: Fe+O2→Fe2O3?
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Solution
Step 1: Tally the number of atoms based on subscript. Fe+O2→Fe2O3 (unbalanced) left side: Fe=1;O=2 right side: Fe=2;O=3
Step 2: Start balancing the simple molecules first, in this case the O2 Fe+3O2→Fe2O3 left side: Fe=1;O=2×3=6 right side: Fe=2;O=3
Since there are now 6O atoms on the left, there must also be 6O atoms on the right. Notice that the right hand is one big molecule so whatever coefficient we would use to balance the O atoms, we would also need to apply to the bonded Fe atom.
Fe+3O2→2Fe2O3 left side: Fe=1;O=2×3=6 right side: Fe=2×2=4;O=3×2=6
Step 3: Now balance the rest of the equation. 4Fe+3O2→2Fe2O3 left side: Fe=1×4=4;O=2×3=6 right side: Fe=2×2=4;O=3×2=6