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Question

(i) Write IUPAC name of CH3CH2NH2.
(ii) Arrange the following amines in the order of their increasing basic strength in aqueous solution.
(CH3)3N1(CH3)2NH1CH3NH2.

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Solution

(i) The IUPAC name of CH3CH2NH2 is ethanamine. Its common name is ethylamine. In IUPAC system, alkyl amines are named as alkanamine.

(ii) The order of their increasing basic strength in aqueous solution is (CH3)3N<CH3NH2<(CH3)2NH.
This is due to a combination of inductive effect, solvation effect, and steric effect.

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