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Question

If the dipole moment of AB molecule is given by 2.4 D and A-B the bond length is 1 A then % covalent character of the bond is:

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Solution

μ is the dipole moment.
The formula to calculate the μ is
μ=e.d , where "e" is the charge of the electron and "d" is the bond legnth 1 Ao
μcal=4.8×1010e.s.u.×108cm=4.8×1018esu.cm=4.8 D.
% of covalent character = μobsμcal×100
% ionic character =2.44.8×100=50%
% co-valent character = 50%

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