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Question

In a hypothetical ionic crystal, B is arranged in cubic close packing and A occupies all octahedral voids and alternative tetrahedral voids. The correct formula of the compound?

A
AB
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B
A2B2
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C
AB2
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D
A2B
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Solution

The correct option is C A2B

No. of atoms ina ccp unit cell is fcc=4

Therefore no. of B atom present =4

No of A atoms= Alternate tetrahedral voids + octahedral voids

=(82+4)=8

The formula of the compound=A8B4 or A2B


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