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Question

In a reaction vessel of 2 liter capacity 3 moles of N2 reacts with 2 moles of O2 to produce 1 mole of NO. What is the molar concentration of N2 at equilibirium ?

A
1.25
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B
1.5
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C
0.75
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D
2
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Solution

The correct option is D 1.25
The equilibrium reaction is N2+O22NO.
The following table list the number of moles of various species.

N2
O2
NO
Initial
3
2
0
Change
-x
-x
2x
Equilibrium
3-x
2-x
2x
But, at equilibrium, the number of moles of NO are 2x or 1. Thus x=0.5.
The number of moles of nitrogen at equilibrium are 3x=30.5=2.5.
The total volume is 2L.
The equilibrium concentration of nitrogen is [N2]=2.52=1.25.

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