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Question

In III group precipitation, NH4Cl is added before adding NH4OH to.

A
Decrease conc. of OH
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B
Prevent interference of PO34
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C
Increase conc. of Cl
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D
Increase conc. of OH ion.
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Solution

The correct option is A Decrease conc. of OH
The common ion effect is responsible for the reduction in the solubility of an ionic precipitate when a soluble compound containing one of the ions of the precipitate is added to the solution in equilibrium with the precipitate.

Due to Common ion effect, the concentration of OH decreases when NH4Cl is added to NH4OH

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