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Question

In the following groups,

(1) OAc

(2) OMe

(3) OSO2Me

(4) OSO2CF3

The order of leaving group ability is:

A
3>2>1>4
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B
1>2>3>4
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C
2>3>4>1
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D
4>3>1>2
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Solution

The correct option is D 4>3>1>2
Leaving group ability1Basicity
Basicty order: OSO2CF3< OSO2Me< OAc< OMe
So, leaving group ability will be opposite to this, i.e.
OSO2CF3>OSO2Me>OAc>OMe
Hence, the correct option is option (b).


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