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Question

In which compound synergic effect is present?

A
[Ni(CO)4]
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B
[NiCl4]2
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C
[CuCl4]2
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D
[Mn(H2O)6]2+
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Solution

The correct option is A [Ni(CO)4]
The MC π bond in metal carbonyl which is formed by the donation of an electron pair from a filled d-orbital of metal into the vacant antibonding π orbital of CO, strengthen the MC σ bond. This is called synergic effect and is usually observed in metal carbonyls. Thus, [Ni(CO)4] exhibit synergic bonding.

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