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Question

In which of the following cases C-C bond length will be highest?

A
CH3CF3
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B
FCH2CH2F
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C
F2CHCHF2
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D
CF3CF3
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Solution

The correct option is B FCH2CH2F
According to Bent's Rule more electronegative substituents attached to hybrid orbital that contains more p-character. Hence, more p-character, longer will be bond length.

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