In which of the following reaction, ether can not be obtained as major product?

M e_{3} C B r + M e O^{⊖} K^{⨁} \to

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M e_{3} C O^{⊖} K^{⨁} + M e B r \to

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C_{2} H_{5} O^{⊖} N a^{⨁} + C H_{3} - B r \to

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R M g X + R O C H_{2} C l \to

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Solution

The correct option is A $M e_{3} C B r + M e O^{⊖} K^{⨁} \to$
The reaction of tert butyl bromide with potassium methoxide gives isobutylene (2-methyl-prop-1-ene) as major product.
$M e_{3} C B r + M e O^{⊖} K^{⨁} \to C H_{2} = C (C H_{3}) C H_{3} i s o b u t y l e n e (2 - m e t h y l - p r o p - 1 - e n e) + C H_{3} - O H + K B r$

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