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Question

In which of the following reactions, H2O2 acts as reducing agent?

A
Cl2+H2O22HCl+O2
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B
H2O2+O3H2O+2O2
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C
HCHO+H2O2HCOOH+H2O
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D
PbO2+H2O2PbO+H2O+O2
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Solution

The correct options are
A Cl2+H2O22HCl+O2
B H2O2+O3H2O+2O2
D PbO2+H2O2PbO+H2O+O2
A reducing agent will undergo a decrease in oxidation state.
Option A: Oxygen undergoes increase in oxidation state from -1 (H2O2) to 0 (O2) i.e. oxidation.

Option B: Oxygen undergoes increase in oxidation state from -1 (H2O2) to 0 (O2) i.e. oxidation.

Option C: Oxygen undergoes decrease in oxidation state from -1 (H2O2) to -2 (H2O) i.e. reduction.

Option D: Oxygen undergoes increase in oxidation state from -1 (H2O2) to 0 (O2) i.e. oxidation.

Hence, the correct options are A, B and D

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