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Question

In which of the following reactions is a carbocation rearrangement possible?

A
(CH3)2CHCH=CH2HCl, 0C−−−−
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B
(CH3)2CHCH=CH2HBr, 0C−−−−−
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C
PhCH2CH=CH2HBr−−
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D
All of these
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Solution

The correct option is D All of these
But since, there is a 30 carbon just next to carbon bearing +ve charge
Rearrangement is possible.
In the exactly similar manner.
This also shows charge rearragement to form.
Charge rearragement is possible in all three.
(d) is correct option.

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