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Sodium Thiosulphate

In which pair...

Question

In which pair of ions both the species contain S - S bond?

S_{4} O_{6}^{2 -}, S_{4} O_{3}^{2 -}

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S_{2} O_{7}^{2 -}, S_{2} O_{8}^{2 -}

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S_{4} O_{6}^{2 -}, S_{2} O_{7}^{2 -}

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S_{2} O_{7}^{2 -}, S_{2} O_{3}^{2 -}

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Solution

The correct option is A $S_{4} O_{6}^{2 -}, S_{4} O_{3}^{2 -}$
Thiosulphate and thionate ions have this:

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S

S_{8}, S_{2} O_{8}^{2 -}, S_{2} O_{3}^{2 -}, S_{4} O_{6}^{2 -}

S - S

S_{4} O_{6}^{2 -}, S_{2} O_{3}^{2 -}, S_{2} O_{8}^{2 -}, S_{2} O_{7}^{2 -}

S_{2} O_{2}^{2 -}, S_{2} O_{3}^{2 -}, S_{2} O_{4}^{2 -}, S_{2} O_{5}^{2 -}, S_{2} O_{6}^{2 -}, S_{2} O_{7}^{2 -}, S_{2} O_{8}^{2 -}

S - S

S = S

‘ x^{'}

S - O - S

‘ y^{'}

‘ z^{'}

(\frac{x}{y + z})

S - S

S_{2} O_{4}^{2 -}, S_{2} O_{6}^{2 -}, S_{2} O_{5}^{2 -}, S_{2} O_{3}^{2 -}, S_{2} O_{7}^{2 -}

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