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Structural and Physical Properties of Carbonyls

Indicate the ...

Question

Indicate the most electronegative carbon in each case:
(a) $C H_{3} - C \equiv C - H$
(b) $C H_{3} - C H_{2} - C H_{2}$

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Solution

a) REF.Image.
SP hybridized carbon is more electronegative.
so
carbon (1) is more electronegative.
b) REF.Image.
$S P^{2}$ hybridized carbon is more electronegative
so
carbon (1) is more electronegative

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What are the hybridization states of each carbon atom(s) in the following molecules ?

(i) $C H_{3} * C H_{2} C H_{2} C H_{3}$

(ii) $C H_{2} = C^{*} H - C H = C H_{2}$

(iii) $C H_{3} * C H = C H - C H_{3}$

(iv) $H - * C \equiv C - H$

S_{N} 2

K I

C H_{3} - C H_{2} - C H_{2} - C H_{2} - C l a n d C H_{3} - C H ∣ C H_{3} - C H_{2} - C l

(I) (I I)

C H_{3} - C H_{2} - C H_{2} - C l a n d C H_{3} - C H_{2} - C H_{2} - B r

(I) (I I)

C H_{3} - C H ∣ C H_{3} - C H_{2} - C H_{2} - C l a n d C H_{3} - C H_{3} ∣ C ∣ C H_{3} - C H_{2} C l

(I) (I I)

C H_{3} - C H_{2} - C H_{2} - B r ∣ C H - C H_{3} a n d C H_{3} - C H_{3} ∣ C H - C H_{2} - B r ∣ C H - C H_{3}

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C H_{3} - C H_{3}, C H_{2} = C H_{2}

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