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Question

Ionic mobility of which of the following alkali metal ions is lowest when aqueous solution of their salts are put under an electric field?

A
Na
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B
K
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C
Rb
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D
Li
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Solution

The correct option is D Li
Li+ ion being smallest, has the maximum charge density.
Li+ is most heavily hydrated among all alkali metal ions. The effective size of Li+ in aqueous solution is therefore, largest.
Li+ moves the slowest under the influence of an electric field.

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