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Question

Li occupies higher position in the electrochemical series of metals as compared to Cu since :

A
The standard reduction potential of Li+/Li is lower than that of Cu2+/Cu
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B
The standard reduction potential of Cu2+/Cu is lower that that of Li/Li
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C
The standard oxidation potential of Li/Li+ is lower than that of Cu/Cu2+
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D
Li is smaller in size as compared to Cu
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Solution

The correct option is D The standard reduction potential of Li+/Li is lower than that of Cu2+/Cu
In the electrochemical series, metals are arranged in increasing order of their standard reduction potential. The standard reduction potential of Li+/Li and Cu2+/Cu are 3.05 V and +0.034 V respectively. Therefore, Li occupies higher position in series as compared to Cu.

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