Major product in Friedel-Craft's acylation of anisole is:-

Chlorobenzene

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4-Chloro-1-methoxy benzene

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4-Methoxy-acetophenone

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3-Methoxy-acetophenone.

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Solution

The correct option is C 4-Methoxy-acetophenone
Friedel-Craft's acylation of anisole with acetyl chloride in presence of anhydrous $A l C l_{3}$ gives 4-methoxy acetophenone(para) as a major product. Methoxy group in anisole is activating and ortho-para directing with major product being para isomer.

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Similar questions

$+ H_{3} C C O C l$ $A n h y . A l C l_{3} - ------ \to$ $X + Y$ .

X is major product. Then Y in the above equation is

2 -

1-Methoxy-2-(2-methoxy ethoxy)ethane

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