Question

Match the reactions with products:

• A. $C_6{H}_5{\mathrm{NH}}_2$
• B. $C_6{H}_5\mathrm{NHOH}$
• C. ${\mathrm{CH}}_3{\mathrm{CH}}_2{\mathrm{CH}}_2{\mathrm{NH}}_2$
• D. ${\mathrm{CH}}_3{\mathrm{CH}}_2{\mathrm{NH}}_2$

Answer 1

${\mathrm{CH}}_3{\mathrm{CH}}_2\mathrm{Cl}\stackrel{\mathrm{Alc}.\mathrm{KOH}}{\to }{\mathrm{CH}}_3{\mathrm{CH}}_2\mathrm{CN}\stackrel{H_2/\mathrm{Ni}}{\to }{\mathrm{CH}}_3{\mathrm{CH}}_2{\mathrm{CH}}_2{\mathrm{NH}}_2$

${\mathrm{CH}}_3{\mathrm{CH}}_2\mathrm{Cl}\underset{{\mathrm{NH}}_3\left(\mathrm{large}\mathrm{excess}\right)}{\overset{\mathrm{Ammonolysis}}{\to }}{\mathrm{CH}}_3{\mathrm{CH}}_2{\mathrm{NH}}_2$