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Question

Natural nitrogen is 99.63% 14N with mass 14.00307 amu and 0.37% 15N, with mass number 15.00011 amu. Which isotope is more stable, 14N or 15N ?
Plan Binding energy per nucleon=m(amu)×931numberofnucleons
Isotope with larger binding energy per nucleon is more stable.

A
7.695 MeV
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B
2.995 MeV
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C
8.8695 MeV
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D
None of these
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Solution

The correct option is A 7.695 MeV
There are 7n, 7p and 7e in 14N
mass of nucleons=7×1.00782505+7×1.008664904
=14.11543 amu
mass defect =14.1154314.00307
=0.11236 amu
binding energy per nucleon =0.11236×93114 MeV
=7.472 MeV
There are 8n, 7p and 7e in N
mass of nucleons=8×1.008664904+7×1.00782505
=15.12409 amu
mass defect =15.1240915.00011
=0.12398 amu
binding energy per nucleon=0.12398×93115MeV
7.695 MeV
As binding energy per nucleon is larger for 15N, hence, 15N is more stable.

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