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Question

Number of hypervalent species among the following ClO−4,BF3,SO2−4,CO2−3

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Solution

A hypervalent molecule (expanded octet) is a molecule that contains one or more main group elements formally bearing more than eight electrons in their valence shells. So ClO−4 is hypervalent as Cl contains more than 8 electrons and SO2−4 is hypervalent as S contains more than 8 electrons. In BF3, boron contains only 6 valence electrons in its outer shell. In CO2−3, the C atom contains 8 electrons in its valence shell.


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