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Inductive Effect

Polarisation ...

Question

Polarisation of electrons in acrolein may be written as :

- δ C H_{2} = C H - + δ C = O

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- δ C H_{2} = C H - C H = + δ O

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- δ C H_{2} = + δ C H - C H = O

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+ δ C H_{2} = C H - C H = - δ O

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Solution

The correct option is D $+ δ C H_{2} = C H - C H = - δ O$
Polarisation of electrons in acrolein may be written as $+ δ C H_{2} = C H - C H = - δ O$ .
O atom is more EN than C atom, so it acquires $(- δ)$ charge and C atom acquires $(+ δ)$ charge which is transferred to the last C atom.

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