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KVPY SA | 2014
Q. At room temperature the average speed of Helium is higher than that of oxygen by a factor of:
  1. 22
  2. 6/2
  3. 8
  4. 6
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Q. The number of CC sigma bonds in the compound is:
631543_947eca942b6f4b92ae53aa11b4dd58aa.png
  1. 18
  2. 16
  3. 17
  4. 11
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Q. The pH of 0.1M aqueous solutions of NaCl, CH3COONa and NH4Cl will follow the order:
  1. NH4Cl<CH3COONa<NaCl
  2. NaCl<CH3COONa<NH4Cl
  3. NH4Cl<NaCl<CH3COONa
  4. NaCl<NH4Cl<CH3COONa
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Q. The numbers of lone pairs and bond pairs in hydrazine are, respectively.
  1. 2 and 5
  2. 2 and 4
  3. 1 and 5
  4. 2 and 6
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Q. The species that exhibits the highest Rf value in a thin layer chromatogram using a non polar solvent on a silica gel plate is?
  1. 631541_2140654_9c89f0e8bddf450e91ab0e2e06aa3c6f.png
  2. 631541_2140655_798d925780cf48c7bce7ca128fd4a1e0.png
  3. 631541_2140656_062fd79d502a44f2bf72e62cd9dec32d.png
  4. 631541_2140657_934d6aeae82c4503896e5c5e5ff07dff.PNG
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Q.

Among the compounds IIV, the compound having the lowest boiling point is:
631559_5d87820b40f14fa3afdfbadcd008b694.png
  1. I
  2. II
  3. III
  4. IV
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Q. The number of isomers which are ethers and having the molecular formula C4H10O is:
  1. 2
  2. 4
  3. 5
  4. 3
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Q. The volume of oxygen at STP required to burn 2.4 g of carbon completely is:
  1. 1.12 L
  2. 2.24 L
  3. 8.96 L
  4. 4.48 L
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Q.
Of the following reactions, the reaction with the largest equilibrium constant is:

(i) AB; ΔGo=250 kJmol1
(ii) D E; ΔGo=100 kJmol1
(iii) F G; ΔGo=150 kJmol1
(iv) MN; ΔGo=150 kJmol1

  1. (i)
  2. (ii)
  3. (iii)
  4. (iv)
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Q. The diamagnetic species is:
  1. NO2
  2. CO2
  3. NO
  4. O2
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Q. The isoelectronic pair is:
  1. O, NO
  2. CO, N2
  3. HF, HCl
  4. C2, HF
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Q. The major product of the reaction of 2-butene with alkaline KMnO4 solution is:
  1. 631558_2140722_c66c0d323a1a4d29ac42901d6efe9ba4.png
  2. 631558_2140723_115387c19fcd4bce9315a6b71c7f735c.png
  3. 631558_2140724_5f3fc09f21724868ac23c38f2b1a2f17.png
  4. 631558_2140725_fea89655ab0c46e281194b7cfbc1c64a.png
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Q. If the radius of the hydrogen atom is 53 pm, the radius of the He+ ion is closest to:
  1. 81 pm
  2. 108 pm
  3. 13 pm
  4. 27 pm
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Q. Ammonia is not produced in the reaction of:
  1. NH4Cl and KOH
  2. AlN with water
  3. NH4Cl with Ca(OH)2
  4. NH4Cl with NaNO2
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Q. The first ionization inthalpies for three elements are 1314, 1680 and 2080 kJ mol1, respectively. The correct sequence of the elements is:
  1. O, F and Ne
  2. F, O and Ne
  3. Ne, F and O
  4. F, Ne and O
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