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KVPY SA [Nov 05] | 2017
Q. In the following reaction the major product is:
738289_239d9a8aab0d47ffb669909ce07438c4.png
  1. 738289_2505861_6d0123c9ed6048c7b92cfedb3935a7a7.png
  2. 738289_2505862_717cde7e4d1d481cafdb1edc7cbb38be.png
  3. 738289_2505863_3311595b90e14f49868e8f14ef9f0bc8.png
  4. 738289_2505864_0d6be78e36a74cbabb7eb6e1523be87d.png
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Q. In the reaction of 1bromo3chlorocyclobutane with two equivalents of sodium in the ether, the major product is:
  1. 738291_2505865_1003ca1209954183b16f5378a6c1b428.png
  2. 738291_2505866_555e5dbf7d1243f48adb818eaec28e43.png
  3. 738291_2505867_92bc21727a7f4e3dbef2cc2ff2485c46.png
  4. 738291_2505868_d1b49fe96d454a4a8ba548935b4b130e.png
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Q. The order of basicity in increasing order is:
738292_976cf09e5f784f778b3b5b05c8c7dcfb.png
  1. IV<I<III<II
  2. II<I<IV<III
  3. IV<III<I<II
  4. II<III<I<IV
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Q. A piece of metal weighing 100 g is heated to 80o C and dropped into 1 kg of cold water in an insulated container at 15o C. If the final temperature of the water in the container is 15.69o C, the specific heat of the metal in J/go.C is:
  1. 0.38
  2. 0.24
  3. 0.45
  4. 0.13
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Q. The structure of 3methylpent2ene is:
  1. 738286_2505845_81ee50772c174403996e8b4da35cc157.png
  2. 738286_2505846_a4dec545e4a440d38fd09b97aeeb730d.png
  3. 738286_2505847_ef81234680794d75986abcbe4c8c552d.png
  4. 738286_2505848_dcadbbe5a7344bd08b9010c4eb926a0d.png
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Q. The reaction of an alkene X with bromine produces a compound Y, which has 22.22%C, 3.71%H and 74.07%Br. The ozonolysis of alkene X gives only one product. The alkene X is?[Given: atomic mass of C=12;H=1;Br=80].
  1. Ethylene
  2. 1-butene
  3. 2-butene
  4. 3-hexene
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Q. The photoelectric behaviour of K, Li, Mg and Ag metals is shown in the plot. If light of wavelength 400nm is incident on each of these metals, which of them will emit photoelectrons? [Planck's constant h=6.626×1034Js; velocity of light c=3×108m s1;1eV=1.6×1019J].
738230_ce6cd9ea558d4c10b52e452a9e9c77d9.png
  1. K
  2. K, Li and Mg
  3. K and Li
  4. K, Li, Mg and Ag
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Q. The stability of carbanions follows the order.
I. CH3CH2CH2CH2
II. CH3CHCH2CH3
III. (CH3)3C
IV. CH3C(Ph)CH2CH3

  1. I<II<IV<III
  2. IV<III<II<I
  3. III<IV<I<III
  4. III<II<I<IV
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Q. KMnO4 reacts with H2O2 in an acidic medium. The number of moles of oxygen produced per mole of KMnO4 is?
  1. 1.25
  2. 2
  3. 2.5
  4. 5
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Q. In the following reaction H3CCCHHg2+H3O+Xdil.NaOHPhCHOY.
X and Y, respectively are:

  1. 738226_2505608_6888880d4f7e4edc91c822f169efb3e8.png
  2. 738226_2505609_fbcbc5c00d8c47a3bf73ba4fc7bb2861.png
  3. 738226_2505610_66f681f31d8940d3aeededb52e24bd00.png
  4. 738226_2505611_1617375d765f431a9cb5005dfcace1bc.png
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