Q. How is benzamide converted into benzylamine?

Q. When $Hg{I}_2$ is added to aqueous solution of KI, why there is an increase in vapour pressure of solution ?

Q. How much amount of substance is deposited by passing one Faraday of electricity?

Q. Write two structure differences between DNA and RNA.

Q. Why does acetylation of $-N{H}_2$ group of aniline reduce its activity ?

Q. Why phenols are acidic in nature ?

Q. Why do transition metals have high enthalpies of atomization?

Q. What are Etard Reaction and Gattermann Koch Reaction ? Give one example of each.

Q. Analysis shows nickel oxide has the formula $N{i}_{0.98}{O}_{1.00}$. What fraction of $Ni$ exists as $N{i}^{2+}$ and $N{i}^{3+}$ ions in given oxide?

Q. Explain $S_{N}1$ mechanism with an example.

Q. Predict the products in the following reaction.

Q. Aldehydes are more reactive toward nucleophillic addition reactions than ketones. Justify.

Q. Calculate the cell potential ($E_{cell}$) of the following cell at $298K$.
$Ag\left(s\right)|AgN{O}_3\left(0.01M\right)||AgN{O}_3\left(1.0M\right)|Ag\left(s\right)$

Q. In a metallic oxide, oxide ions are arranged in cubic close packing. One sixth of the tetrahedral voids are occupied by cations $P$ and one third of octahedral voids are occupied by the cation $Q$. Deduce the formula of the compound.

Q. What are biodegradable polymers ? Give chemical equation for the preparation of any one biodegradable polymer.

Q. Explain metal deficiency defect due to cation vacancies.

Q. For a reaction rate law expression is:
Rate $=K\left[A{]}^{1/2}\right[B{]}^2$
Can this reaction be an elementary? Explain.

Q. Explain normal or standard hydrogen electrode.

Q. Explain the mechanism of the following reaction.
$C_2{H}_{5}OH\underset{443K}{\overset{Conc.H_{2}S{O}_4}{\to }}C{H}_2=C{H}_2+H_{2}O$

Q. Give two differences between macromolecular colloids and associated colloids.

Q. What is Tollen's reagent ?

Q. Explain the term dialysis. How can it be increased ?

Q. What are the units of rate constant for the first order reaction?

Q. What are Claisen schmidt condensation and Kolbe's Reaction ? Give one example of each.

Q. Why $NC{l}_3$ and $PC{l}_3$ are hydrolysed differently?

Q. Why $H_{3}P{O}_4$ is triprotic acid but $H_{3}P{O}_3$ is diprotic acid?

Q. Commercially available $HCl$ contains $38\%$ $HCl$ by mass. Calculate molality of the solution.

Q. Explain Mond's process used for refining of nickel.

Q. Out of $1M$ urea solution and $1MKCl$ solution, which one has higher freezing point ?

Q. $\left[Fe\right(CN{)}_6{]}^{-3}$ is low spin complex but $\left[Fe\right(H_{2}O{)}_6{]}^{+3}$ is high spin complex. Explain.