The correct option is D a pair of cation and anion vacancies
Schottky defect in solids is due to a pair of cation and anion vacancies. Equal number of cations and anions are missing which ensures electrical neutrality. Due to this defect, the density of crystal decreases.
Frenkel defect in solids is due to occupation of interstitial site by a cation or an anion. This defect does not affects the density of the crystal.