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Crystal Field Split in Octahedral Complexes

Select the co...

Question

Select the correct options for following statement(s) :

s p^{3}

hybrid orbitals are at

90^{0}

to one another

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s p^{3} d^{2}

adjacent hybrid orbitals are at

90^{0}

to one another

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s p^{2}

hybrid orbitals are at

120^{0}

to one another

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Bond order of

N - O

bond in

N O_{3}^{-}

1 \frac{1}{3} .

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Solution

The correct options are
B $s p^{3} d^{2}$ adjacent hybrid orbitals are at $90^{0}$ to one another
C $s p^{2}$ hybrid orbitals are at $120^{0}$ to one another
D Bond order of $N - O$ bond in $N O_{3}^{-}$ is $1 \frac{1}{3} .$

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Question 03

The types of hybrid orbitals of nitrogen in $N O_{2}^{+}, N O_{3}^{-} a n d N H_{4}^{+}$ respectively are expected to be

(a) $s p, s p^{3} a n d s p^{2}$

(b) $s p, s p^{2} a n d s p^{3}$

(d) $s p^{2}, s p^{3} a n d s p$

s p^{3}

90^{\circ}

s p - d^{2}

90^{\circ}

s p^{2}

120^{\circ}

N - O

{N O}_{3}^{-}

\frac{1}{3}

s p, s p^{2}, s p^{3}

s p^{3}, s p^{2}, s p

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