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Question

State True or False.
The bond angle around B in BCl3 and BF3 is same.

A
True
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B
False
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Solution

The correct option is B False
The given statement is False.
The bond angle around B in BCl3 is higher than the bond angle around B in BF3. F is more electronegative than Cl. Hence, the bond pair of electrons of BF bond are more towards F and away from B whereas the bond pair of electrons of BCl bond are away Cl and more towards B. closer are the bond pair of electrons towards B, greater is interelectronic repulsion and greater is the bond angle.

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