The alcohol which gives the most stable carbonium ion on dehydration is:
A
(CH3)2CHCH2OH
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B
(CH3)3C−OH
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C
CH3CH2CH2CH2OH
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D
CH3−CH−CH2CH3
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Solution
The correct option is B(CH3)3C−OH Tert-butanol loses an −OH group to give most stable carbonium ion. The positive charge on carbon atom is stabilized by +I inductive effect of 3 methyl groups.