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Question

The best reagent for converting, 2-phenylpropanamide into 1-phenylethanamine is:

A
excess H2/Pt
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B
NaOH/Br2
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C
NaBH4/methanol
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D
LiAlH4/ether
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Solution

The correct option is A NaOH/Br2
By Hoffmann bromamide degradation reaction, tha amine formed contains one carbon less than that present in the amide.

CH3C6H5|CHCONH2+Br2+4NaOHCH3C6H5|CHNH2+Na2CO3+2NaBr+2H2O
2-phenylpropanamide 1-phenylethanamine

Option B is correct.

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