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Byju's Answer
Standard XII
Chemistry
Curtius and Hofmann Rearrangements
The best reag...
Question
The best reagent for converting, 2-phenylpropanamide into 1-phenylethanamine is:
A
excess
H
2
/
P
t
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B
N
a
O
H
/
B
r
2
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C
N
a
B
H
4
/
methanol
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D
L
i
A
l
H
4
/
ether
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Solution
The correct option is
A
N
a
O
H
/
B
r
2
By Hoffmann bromamide degradation reaction, tha amine formed contains one carbon less than that present in the amide.
C
H
3
−
C
6
H
5
|
C
H
−
C
O
N
H
2
+
B
r
2
+
4
N
a
O
H
→
C
H
3
−
C
6
H
5
|
C
H
−
N
H
2
+
N
a
2
C
O
3
+
2
N
a
B
r
+
2
H
2
O
2-phenylpropanamide 1-phenylethanamine
Option B is correct.
Suggest Corrections
0
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