The carbon – based reduction method is not used for the extraction of
aluminium from Al2O3
magnesium from MgCO3,CaCO3
AI has greater affinity for oxygen, hence oxide is not reduced by carbon. MgO and CaO (formed in the calcination from carbonates) are stable species and not reduced by carbon.
During Smelting SnO2+C1300∘C−−−−→Sn+CO2
2Fe2O3 3CΔ−→4Fe+3CO2