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Question

The CFSE for [Fe(CN)6]3 is



A

1.2Δ

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B

2.0Δ

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C

1.8Δ

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D

+1.2Δ

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Solution

The correct option is B

2.0Δ


CFSE=(0.4×t2ge)+0.6×ege

= (0.4×5×Δ)+(0.6×0×Δ)=2.0Δ

Splitting of degenerate –d-orbitals in octahedral strong field.


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