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Question

The complexes  $$[Co(NH_{3})_{6}][Cr(CN)_{6}]and [Cr(NH_{3})_{6}][Co(CN)_{6}]$$ are the examples of which type of isomerism?


A
Linkage isomerism
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B
Ionization isomerism
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C
Coordination isomerism
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D
Geometrical isomerism
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Solution

The correct option is C Coordination isomerism
Option (C) is correct. The complexes  $$[Co(NH_{3})_{6}][Cr(CN)_{6}]$$ and $$[Cr(NH_{3})_{6}][Co(CN)_{6}]$$ are the example of coordination isomerism.

In coordination isomerism, both positive and negative ions of a salt are complex ions and the two isomers differ in the distribution of ligands between the cation and the anion.

Chemistry

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