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Question

The correct sequence of increasing melting point of BeCl2,MgCl2,CaCl2,SrCl2 and BaCl2 is

A
BaCl2<SrCl2<CaCl2<MgCl2<BeCl2
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B
BeCl2<MgCl2<CaCl2<SrCl2<BaCl2
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C
BeCl2<CaCl2<MgCl2<SrCl2<BaCl2
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D
MgCl2<BeCl2<SrCl2<CaCl2<BaCl2
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Solution

The correct option is B BeCl2<MgCl2<CaCl2<SrCl2<BaCl2
Ionic character depends upon, electronegativity difference between cation and anion of the compound. As these difference increases, the ionic character increases. The larger the size of cation and the smaller the size of anion, the more is the electronegativity difference and the more is the ionic character. as here anion is same and sequence of the size of the cation is Be2+<Mg2+<Ca2+<Sr2+<Ba2+

So the correct order of M.P is as follows: BeCl2<MgCl2<CaCl2<SrCl2<BaCl2 Hence, option B is correct

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