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The decomposition of N2O5 in chloroform was followed by measuring the volume of O2 gas evolved: 2N2O5(CCl4) -------> 2N2O4(CCl4)+O2(g). The maximum volume of O2 gas obtained was 100cm^3. In 500 minutes ,90 cm^3 of O2 were evolved . The first order rate constant (in min^-1 ) for the disappearance of N2O5 is

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