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Question

The difference between the heats of reaction at constant pressure and constant volume for the reaction.
2C6H6(l)+15O2(g) 12CO2(g)+6H2O(l)at25C in kJ is:

A
7.43
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B
+3.72
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C
3.72
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D
+7.43
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Solution

The correct option is B 7.43
The difference between heats of reaction at constant pressure and constant volume for the following reaction at 25 degree Celsius in kJ
2C6H6(l)+15O2(g)12CO2(g)+6H2O
Δn=1215=3
ΔH=ΔE+RTΔn
ΔHΔE=RTΔn
=(3)×8.314×103×298
=7.43 kJ/mol

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