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Question

The equilibrium constant for a reaction A+BC+D is 1×102 at 298K and is 2 at 273 K. The chemical process resulting in the formation of C and D is:

A
Exothermic
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B
Endothermic
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C
Unpredictable
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D
There is no relationship ΔH and K.
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Solution

The correct option is A Exothermic
With increase in temperature from 273 K to 298 K, the value of the equilibrium constant decreases from 2 to 1×102. Thus as the temperature increases, the equilibrium shifts to left. This is possible for an exothermic reaction.
Thus the process resulting in the formation of C and D is an exothermic reaction.

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