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Question

The equivalent conductivity of monobasic acid at infinite dilution is 348 ohm−1 cm2 eq−1. If the resistivity of the solution containing 15 g acid (molar mass 49) in 1 litre is 18.5 ohm cm, what is the degree of dissociation of acid?

A
45.9%
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B
40.2%
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C
60.4%
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D
50.7%
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Solution

The correct option is D 50.7%
equivalent conductivity of monobar'c acid at infinite dilution m=348Ω1cm2eq1
Amount of acid =15g
Molar mass =49
Molarity = 1549/1litre=0.306M
Resistivity = 18.5 ohm cm
conductivity = 118.5=0.054
Molar conductivity = 0.0540.306×103
m=176.64
dissociation constant α=mm=176.64348
=0.507
50.7%
option D

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