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Question

The Henry's law constant for the solubility of N2 gas in water at 298K is 1×105 atm. The mole fraction of N2 in air is 0.8. Calculate the number of moles of N2 dissolved in 10moles of water at 298K and 5atm.

A
5×104
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B
3×105
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C
4×104
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D
4×105
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Solution

The correct option is D 4×104
Given,

Pt = 5 atm.
XN2 = 0.8
KH = 1×105 atm

The partial pressure of nitrogen is 0.8×5=4 atm

According to Henry's law, P=KH×X

Substituting values in the above expression, we get -

X=4atm1×105atm=4×105

1 mole of water contains 4×105 moles of N2.

10 moles of water contains 4.0×104 mol

Hence, option C is correct.

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