The molecular weight of benzoic acid in benzene as determined by depression in the freezing point method corresponds to:
A
ionization of benzoic acid
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B
dimerization of benzoic acid
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C
trimerization of benzoic acid
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D
solvation of benzoic acid
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Solution
The correct option is B dimerization of benzoic acid The molecular weight of benzoic acid in benzene is determined by the depression in freezing point method and comes out to be 244. The actual molecular mass is 122. Therefore, it corresponds to the dimers which are formed by hydrogen bonding.