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Question

The most suitable reagent for the conversion of RCH2OHRCHO is :

A
CrO3
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B
PCC (Pyridinium Chlorochromate)
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C
KMnO4
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D
K2Cr2O7
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Solution

The correct option is B PCC (Pyridinium Chlorochromate)
The most suitable reagent for the conversion of RCH2OHRCHO is PCC (Pyridinium Chlorochromate).
Primary alcohols are oxidized to aldehydes. Aldehydes are further oxidized to carboxylic acids.
PCC (Pyridinium Chlorochromate) is a mild oxidizing agent. it oxidizes primary alcohols to aldehydes only. The further oxidation to carboxylic acid does not occur.
CrO3, KMnO4 and K2Cr2O7 are strong oxidizing agents. They oxidize primary alcohol to aldehdye and further to carboxylic acid.

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