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Question

The oxidation number of Ni in K4[Ni(CN)4] is :

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Solution

Let x be the oxidation state of Ni in K4[Ni(CN)4].
Since the overall charge on the complex is 0, the sum of oxidation states of all elements in it should be equal to 0.
Therefore,
+4+x4=0
or, x=0.
Hence,
the oxidation state of Ni in K4[Ni(CN)4] is 0.

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