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Question

The oxidation number of Ni in Ni(CO)4 is +2.

A
True
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B
False
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C
Anomalous
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D
None of these
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Solution

The correct option is B False
Let x be the oxidation number of Ni in Ni(CO)4.
Since the overall
charge on the complex is 0, the sum of oxidation states of all elements in
it should be equal to 0.
Therefore, x+4(0)=0
Hence, x=0.
Thus, the oxidation number of Ni in Ni(CO)4 is 0.

Hence, the correct option is B

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