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Question

The percentage composition of sodium phosphate as determined by analysis is 42.1% sodium, 18.9 % phosphorus and 39 % oxygen. Find the empirical formula of the compound[Na = 23, P = 31, O = 16].

A
Na3PO3
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B
NaPO4
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C
Na2PO4
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D
Na3PO4
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Solution

The correct option is D Na3PO4
ElementPercentage composition Atomic weight Relative No. of atoms Simplest ratio
Sodium42.1 2342.1/23 = 1.83 1.83/0.61 = 3
Phosphorus18.9 3118.9/31 = 0.610.61/0.61 = 1
Oxygen39.0 1639.0/16 = 2.442.44/0.61 = 4
Thus empirical formula is Na3PO4.

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