The reaction of benzenesulphonyl chloride with ethylamine yields:
A
N-ethylbenzenesulphonamide, insoluble in alkali
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B
N, N-diethylbenzenesulphonamide, soluble in alkali
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C
N, N-diethylbenzenesulphonamide, insoluble in alkali
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D
N-ethylbenzenesulphonamide, soluble in alkali
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Solution
The correct option is D N-ethylbenzenesulphonamide, soluble in alkali
C2H4NH2C6H5SO2Cl−−−−−−−→C6H5SO2NHC2H5
Primary amine (ethylamine) react with benzenesulphonyl chloride to form N-ethylbenzenesulphonamide, which is soluble with alkali, through the formation of salt.